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How Charles Hall Invented Modern Aluminum Production

This 1889 patent describes the Hall-Héroult process, which uses electricity to extract pure aluminum from its ore, making the metal affordable for everyone.

Granted 1889ExpiredExpired 1906Owned by IndividualInvented by M Hall Charles

Original patent title: “Process of reducing aluminium from its fluoride salts by electrolysis

Plain-English explanation by SahiLast reviewed · June 13, 2026

This 1889 patent describes the Hall-Héroult process, which uses electricity to extract pure aluminum from its ore, making the metal affordable for everyone. Granted to Individual in 1889 with 18 forward citations, and it is now in the public domain.

Coverage

What does this patent actually cover?

The patent details a method for isolating aluminum by dissolving aluminum oxide in a bath of molten cryolite. An electric current is then passed through this mixture, causing the aluminum to separate and collect at the bottom of the vessel. This process effectively lowers the melting point of the aluminum ore, allowing it to be processed at temperatures that are commercially practical.

The gap

What does this patent NOT cover?

  • Does not cover chemical reduction methods that rely on heat alone without electrolysis
  • Does not cover the refining of aluminum from non-fluoride salts
  • Does not cover the specific design of the industrial smelting pots used in modern plants

These exclusions are unique to PatentBrief — derived from the actual claim language, not patent-office boilerplate.

Key facts

Patent numberUS 400664
StatusExpired
FieldEnergy & Clean Tech
AssigneeIndividual
InventorM Hall Charles
Filed1886
Granted1889
Expires1906 (expired)
Times cited18
LitigationNone on record
Value · $22K$69KMinimal

What made this novel

The genius was realizing that molten cryolite acts as a solvent for aluminum oxide, allowing electrolysis to occur at a much lower temperature than melting the oxide alone.

The Patent Drawing

Representative patent drawing for Process of reducing aluminium from its fluoride salts by electrolysis (US 400664)
Representative figure · US 400664All figures on Google Patents →
Process of reducing aluminium …(Primary claim)mechanicalenergymaterials

Schematic visualization of the patent's claim structure. Hand-drawn diagrams in progress for each landmark patent.

Where you've seen this

Real-world examples

01

Modern aluminum smelting plants

02

Production of aluminum foil

03

Manufacturing of lightweight automotive parts

04

Aerospace structural components

Why it matters

The bigger picture

Before this invention, aluminum was more expensive than gold because it was incredibly difficult to extract. This process transformed aluminum from a luxury material into a common industrial metal used in everything from airplanes to soda cans.

Filed

July 9, 1886

Granted

April 2, 1889

Market context

Who's building on this

Companies in this space

Major global aluminum producers like Alcoa, which traces its roots back to the company founded to exploit this patent, continue to refine this fundamental electrolytic process.

Market impact

This patent effectively launched the modern aluminum industry, enabling the mass production required for the 20th-century boom in aerospace, construction, and consumer packaging.

Claim 1 — Plain English

What this patent covers

The patent details a method for isolating aluminum by dissolving aluminum oxide in a bath of molten cryolite. An electric current is then passed through this mixture, causing the aluminum to separate and collect at the bottom of the vessel. This process effectively lowers the melting point of the aluminum ore, allowing it to be processed at temperatures that are commercially practical.

The clever bit

The genius was realizing that molten cryolite acts as a solvent for aluminum oxide, allowing electrolysis to occur at a much lower temperature than melting the oxide alone.

What it does not cover

  • Does not cover chemical reduction methods that rely on heat alone without electrolysis
  • Does not cover the refining of aluminum from non-fluoride salts
  • Does not cover the specific design of the industrial smelting pots used in modern plants

Patent timeline

Filing

Application submitted to the patent office

Publication

Application published, typically 18 months after filing

Grant

Patent officially issued

Expiration

Patent enters public domain

This patent is in the public domain

See the Freedom to Build guide — what is free to use, what is not, and how to cite this patent.

View guide →

PatentBrief Score

Impact Score

Early stage

Citation count

26/40

Moderately cited

Claim breadth

0/20

Narrow claimsclaimsThe numbered statements at the end of a patent that legally define what the inventor owns.Read more →

Recency

0/20

Older than 20 years

Assignee scale

0/20

Independent or smaller assigneeassigneeThe entity that owns the patent — usually the inventor's employer or a company.Read more →

PatentBrief Impact Score — based on citation count, claim breadth, recency, and assignee scale. Not a legal assessment.

Heuristic Value Estimate

What this patent might be worth

Minimal

$22K$69K

Midpoint $43K · expired or expiring · industry ×2.4

Adjust inputs →

Heuristic only — blends forward/backward citation counts, claim scope, time remaining, litigation history, and CPC-derived industry baseline. Real valuations need a professional appraisal.

Claim text not yet imported for this patent

Claim text not yet imported for this patent.

Concepts involved

ClaimPrior artNon-obviousnessNoveltySpecificationAssigneePatent term

Citations

Patent lineage

Cited by later patents

18

later patents that build on this invention

View patents →

Cite this patent

Charles, M. H. (1889). How Charles Hall Invented Modern Aluminum Production (U.S. Patent No. 400,664). U.S. Patent and Trademark Office. https://patentbrief.org/patent/us/400664/hall-process-aluminum-smelting

Auto-generated from the patent record. Double-check author order and the issue date against the official USPTO document before submitting.

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Common Questions

Frequently Asked Questions

What does How Charles Hall Invented Modern Aluminum Production cover?

This 1889 patent describes the Hall-Héroult process, which uses electricity to extract pure aluminum from its ore, making the metal affordable for everyone.

Who owns patent US 400664?

Individual owns this patent, granted in 1889.

When does this patent expire?

This patent has expired and is now in the public domain — anyone can use the invention freely.

What is patent US 400664 cited by?

This patent has been cited by 18 later patents that build on its ideas.

What problem does this patent solve?

Before this invention, aluminum was more expensive than gold because it was incredibly difficult to extract. This process transformed aluminum from a luxury material into a common industrial metal used in everything from airplanes to soda cans.

What does this patent NOT cover?

Does not cover chemical reduction methods that rely on heat alone without electrolysis

Same assignee

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Last reviewed: June 13, 2026 · PatentBrief is not a law firm and this is not legal advice.