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Making Caustic Soda with Less Salt Using a Special Electrolysis Cell

This patent describes a method to make purer caustic soda and chlorine gas using a two-chamber electrolysis cell with a gas diffusion electrode by carefully controlling pressure differences.

Granted 2015ActiveExpires 2030Owned by Chlorine Engineers CorpInvented by Mikihito Sugiyama, Kiyohito Asaumi, Yukinori Iguchi

Original patent title: “Method of electrolysis employing two-chamber ion exchange membrane electrolytic cell having gas diffusion electrode

Plain-English explanation by SahiLast reviewed · July 16, 2026

This patent describes a method to make purer caustic soda and chlorine gas using a two-chamber electrolysis cell with a gas diffusion electrode by carefully controlling pressure differences. Granted to Chlorine Engineers Corp in 2015 with 9 claims and 7 forward citations, and it is expected to expire in 2030.

Coverage

What does this patent actually cover?

The patent claimsclaimsThe numbered statements at the end of a patent that legally define what the inventor owns.Read more → a method for electrolyzing brine (saltwater) in a "two-chamber ion exchange membrane electrolytic cell" (ClaimclaimA numbered sentence at the end of a patent that legally defines what the inventor owns. The most important section.Read more → 1). This cell has an "anode chamber" and a "cathode gas chamber" separated by an "ion exchange membrane." The cathode chamber uses a "gas diffusion electrode." The core idea is "reducing a differential pressure" between the liquid pressure in the anode chamber and the gas pressure in the cathode gas chamber (Claim 1). This pressure difference is precisely controlled, for example, reduced to "2.4 kPa or less" (Claim 1) or "-21.6 kPa or more" (Claim 2), by adjusting a "sealing pot or a valve" (Claim 1). This precise pressure control helps in "decreasing a salt concentration in the caustic soda aqueous solution" (Claim 1). For example, by carefully adjusting the valve downstream of the cathode chamber, the pressure inside the cathode chamber can be increased, which reduces the pressure difference across the membrane, leading to purer caustic soda.

The gap

What does this patent NOT cover?

  • Electrolysis methods that do not use a "two-chamber ion exchange membrane electrolytic cell."
  • Electrolysis cells that do not employ a "gas diffusion electrode" as the cathode.
  • Methods that do not involve reducing the differential pressure between the anode liquid and cathode gas.
  • Methods where the differential pressure is not controlled to be "2.4 kPa or less" or "-21.6 kPa or more."
  • Electrolysis processes for producing chemicals other than chlorine gas and caustic soda.

These exclusions are unique to PatentBrief — derived from the actual claim language, not patent-office boilerplate.

Key facts

Patent numberUS 9181624
StatusActive
FieldEnergy & Clean Tech
AssigneeChlorine Engineers Corp
InventorsMikihito Sugiyama, Kiyohito Asaumi, Yukinori Iguchi
Filed2010
Granted2015
Expires2030
Claims9
Times cited7
LitigationNone on record
Value · $101K$323KModest

What made this novel

The noveltynoveltyThe requirement that an invention be different from anything publicly known before its priority date.Read more → lies in precisely managing the pressure difference across the ion exchange membrane in a two-chamber cell with a gas diffusion electrode. By reducing this "differential pressure" to specific narrow ranges (e.g., 2.4 kPa or less), the method significantly lowers the unwanted salt concentration in the produced caustic soda solution.

The Patent Drawing

Representative patent drawing for Method of electrolysis employing two-chamber ion exchange membrane electrolytic cell having gas diffusion electrode (US 9181624)
Representative figure · US 9181624All figures on Google Patents →
Method of electrolysis employi…(Primary claim)chemical manufacturingenergymaterialsindustrial processes

Schematic visualization of the patent's claim structure. Hand-drawn diagrams in progress for each landmark patent.

Where you've seen this

Real-world examples

01

Chlor-alkali plants

02

Manufacturing of PVC (polyvinyl chloride)

03

Water treatment facilities

04

Pulp and paper production

05

Textile bleaching

Why it matters

The bigger picture

Caustic soda (sodium hydroxide) and chlorine gas are fundamental chemicals used in countless industries, from making paper and plastics to purifying water. Producing these chemicals with lower salt impurities, as described in this patent, means the final products are cleaner and more valuable. This improved purity can reduce downstream processing costs and enhance the quality of products made using these chemicals.

Filed

April 15, 2010

Granted

November 10, 2015

Market context

Who's building on this

Companies in this space

Chlorine Engineers Corp Ltd, the original assigneeassigneeThe entity that owns the patent — usually the inventor's employer or a company.Read more →, is a key player in chlor-alkali technology. Other major companies in the chlor-alkali industry, such as Asahi Kasei, thyssenkrupp Uhde Chlorine Engineers, and Covestro, continuously work on improving electrolysis cell efficiency and product purity.

Market impact

This patent contributes to the ongoing drive for higher efficiency and purity in the chlor-alkali industry. By enabling the production of caustic soda with lower salt content, it supports the creation of higher-grade chemicals, which can command better prices and reduce the need for further purification steps. This improvement helps maintain competitiveness and meet stringent quality standards in various downstream industries.

Claim 1 — Plain English

What this patent covers

The patent claims a method for electrolyzing brine (saltwater) in a "two-chamber ion exchange membrane electrolytic cell" (Claim 1). This cell has an "anode chamber" and a "cathode gas chamber" separated by an "ion exchange membrane." The cathode chamber uses a "gas diffusion electrode." The core idea is "reducing a differential pressure" between the liquid pressure in the anode chamber and the gas pressure in the cathode gas chamber (Claim 1). This pressure difference is precisely controlled, for example, reduced to "2.4 kPa or less" (Claim 1) or "-21.6 kPa or more" (Claim 2), by adjusting a "sealing pot or a valve" (Claim 1). This precise pressure control helps in "decreasing a salt concentration in the caustic soda aqueous solution" (Claim 1). For example, by carefully adjusting the valve downstream of the cathode chamber, the pressure inside the cathode chamber can be increased, which reduces the pressure difference across the membrane, leading to purer caustic soda.

The clever bit

The novelty lies in precisely managing the pressure difference across the ion exchange membrane in a two-chamber cell with a gas diffusion electrode. By reducing this "differential pressure" to specific narrow ranges (e.g., 2.4 kPa or less), the method significantly lowers the unwanted salt concentration in the produced caustic soda solution.

What it does not cover

  • Electrolysis methods that do not use a "two-chamber ion exchange membrane electrolytic cell."
  • Electrolysis cells that do not employ a "gas diffusion electrode" as the cathode.
  • Methods that do not involve reducing the differential pressure between the anode liquid and cathode gas.
  • Methods where the differential pressure is not controlled to be "2.4 kPa or less" or "-21.6 kPa or more."
  • Electrolysis processes for producing chemicals other than chlorine gas and caustic soda.

Patent timeline

Filing

Application submitted to the patent office

Publication

Application published, typically 18 months after filing

Grant

Patent officially issued

Expiration

Patent enters public domain

PatentBrief Score

Impact Score

Early stage

Citation count

18/40

Early citations

Claim breadth

6/20

Moderate scope

Recency

5/20

Granted 10–20 years ago

Assignee scale

0/20

Independent or smaller assigneeassigneeThe entity that owns the patent — usually the inventor's employer or a company.Read more →

PatentBrief Impact Score — based on citation count, claim breadth, recency, and assignee scale. Not a legal assessment.

Heuristic Value Estimate

What this patent might be worth

Modest

$101K$323K

Midpoint $202K · 3.7 yr remaining · industry ×2.4

Adjust inputs →

Heuristic only — blends forward/backward citation counts, claim scope, time remaining, litigation history, and CPC-derived industry baseline. Real valuations need a professional appraisal.

Claim text not yet imported for this patent

The original legal language

Original claims

9 claims as filed with the patent office.

Concepts involved

ClaimPrior artNon-obviousnessNoveltySpecificationAssigneePatent term

Citations

Patent lineage

Cites earlier patents

23

earlier patents this invention cites as foundations

View prior art →

Cited by later patents

7

later patents that build on this invention

View patents →

Cite this patent

Sugiyama, M., Asaumi, K., & Iguchi, Y. (2015). Making Caustic Soda with Less Salt Using a Special Electrolysis Cell (U.S. Patent No. 9,181,624). U.S. Patent and Trademark Office. https://patentbrief.org/patent/us/9181624/method-of-electrolysis-employing-two-chamber-ion-exchange-membrane-electrolytic-

Auto-generated from the patent record. Double-check author order and the issue date against the official USPTO document before submitting.

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Common Questions

Frequently Asked Questions

What does Making Caustic Soda with Less Salt Using a Special Electrolysis Cell cover?

This patent describes a method to make purer caustic soda and chlorine gas using a two-chamber electrolysis cell with a gas diffusion electrode by carefully controlling pressure differences.

Who owns patent US 9181624?

Chlorine Engineers Corp owns this patent, granted in 2015.

When does this patent expire?

This patent is expected to expire on April 15, 2030, when the invention enters the public domain.

What is patent US 9181624 cited by?

This patent has been cited by 7 later patents that build on its ideas.

What problem does this patent solve?

Caustic soda (sodium hydroxide) and chlorine gas are fundamental chemicals used in countless industries, from making paper and plastics to purifying water. Producing these chemicals with lower salt impurities, as described in this patent, means the final products are cleaner and more valuable. This improved purity can reduce downstream processing costs and enhance the quality of products made using these chemicals.

What does this patent NOT cover?

Electrolysis methods that do not use a "two-chamber ion exchange membrane electrolytic cell."

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Last reviewed: July 16, 2026 · PatentBrief is not a law firm and this is not legal advice.