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How Wallace Carothers Invented Nylon

The foundational 1935 patent for synthetic linear polyamides, the chemical process that created the material we now call nylon.

Granted 1938ExpiredExpired 1955Owned by EI Du Pont de Nemours and CoInvented by Wallace H Carothers

Original patent title: “Linear polyamides and their production

Plain-English explanation by SahiLast reviewed · June 13, 2026

The foundational 1935 patent for synthetic linear polyamides, the chemical process that created the material we now call nylon. Granted to EI Du Pont de Nemours and Co in 1938 with 299 forward citations, and it is now in the public domain.

Often confused with

US 2,130,948 ("Synthetic Fiber") — also invented by Wallace Carothers for DuPont and granted the very same day, September 20, 1938. The difference: this patent (US 2,130,523, "Linear polyamides and their production") covers the linear polyamide polymer itself — the nylon material, filed in 1935 — while US 2,130,948 covers spinning that polyamide into strong, oriented textile fibers (filed 1937). This page is the foundational nylon composition patent; US 2,130,948 is its companion fiber patent.

Coverage

What does this patent actually cover?

This patent describes the chemical synthesis of high-molecular-weight linear polyamides by heating diamines with dibasic acids. By controlling the polymerization process, the inventorinventorThe person who actually conceived the invention. Listed on the patent regardless of who owns it.Read more → created long-chain molecules that could be drawn into strong, flexible fibers. This process transformed simple chemical building blocks into a material capable of replacing natural silk in textiles and industrial applications.

The gap

What does this patent NOT cover?

  • Does not cover non-linear or branched polyamide structures.
  • Does not cover the specific manufacturing machinery used for spinning the fibers.
  • Does not cover the use of polyamides in non-fiber applications like molded plastics.

These exclusions are unique to PatentBrief — derived from the actual claim language, not patent-office boilerplate.

Key facts

Patent numberUS 2130523
StatusExpired
FieldMaterials & Manufacturing
AssigneeEI Du Pont de Nemours and Co
InventorWallace H Carothers
Filed1935
Granted1938
Expires1955 (expired)
Times cited299
LitigationNone on record
Value · $24K$77KMinimal

What made this novel

Carothers discovered that by maintaining a precise stoichiometric balance and removing water during heating, he could force the molecules to link into long, stable chains rather than short, useless clumps.

Linear polyamides and their pr…(Primary claim)materialschemical engineering

Schematic visualization of the patent's claim structure. Hand-drawn diagrams in progress for each landmark patent.

Where you've seen this

Real-world examples

01

Nylon stockings

02

Parachute cords

03

Toothbrush bristles

04

Fishing line

Why it matters

The bigger picture

This patent marks the birth of the synthetic fiber industry. It allowed DuPont to mass-produce nylon, which became a critical material for everything from hosiery to parachutes during World War II.

Filed

January 2, 1935

Granted

September 20, 1938

Market context

Who's building on this

Companies in this space

DuPont remains a major player in the polyamide market, but the core chemistry is now foundational knowledge used by global chemical giants like BASF and Lanxess to produce various grades of nylon for automotive and industrial parts.

Market impact

This patent effectively created the multi-billion dollar synthetic fiber market. It shifted global reliance away from natural fibers like silk and cotton toward engineered materials, permanently altering the global supply chain for clothing and industrial components.

Claim 1 — Plain English

What this patent covers

This patent describes the chemical synthesis of high-molecular-weight linear polyamides by heating diamines with dibasic acids. By controlling the polymerization process, the inventor created long-chain molecules that could be drawn into strong, flexible fibers. This process transformed simple chemical building blocks into a material capable of replacing natural silk in textiles and industrial applications.

The clever bit

Carothers discovered that by maintaining a precise stoichiometric balance and removing water during heating, he could force the molecules to link into long, stable chains rather than short, useless clumps.

What it does not cover

  • Does not cover non-linear or branched polyamide structures.
  • Does not cover the specific manufacturing machinery used for spinning the fibers.
  • Does not cover the use of polyamides in non-fiber applications like molded plastics.

Patent timeline

Filing

Application submitted to the patent office

Publication

Application published, typically 18 months after filing

Grant

Patent officially issued

Expiration

Patent enters public domain

This patent is in the public domain

See the Freedom to Build guide — what is free to use, what is not, and how to cite this patent.

View guide →

PatentBrief Score

Impact Score

Moderate

Citation count

40/40

Highly cited

Claim breadth

0/20

Narrow claimsclaimsThe numbered statements at the end of a patent that legally define what the inventor owns.Read more →

Recency

0/20

Older than 20 years

Assignee scale

0/20

Independent or smaller assigneeassigneeThe entity that owns the patent — usually the inventor's employer or a company.Read more →

PatentBrief Impact Score — based on citation count, claim breadth, recency, and assignee scale. Not a legal assessment.

Heuristic Value Estimate

What this patent might be worth

Minimal

$24K$77K

Midpoint $48K · expired or expiring · industry ×0.8

Adjust inputs →

Heuristic only — blends forward/backward citation counts, claim scope, time remaining, litigation history, and CPC-derived industry baseline. Real valuations need a professional appraisal.

Claim text not yet imported for this patent

Claim text not yet imported for this patent.

Concepts involved

ClaimPrior artNon-obviousnessNoveltySpecificationAssigneePatent term

Citations

Patent lineage

Cited by later patents

299

later patents that build on this invention

View patents →

Cite this patent

Carothers, W. H. (1938). How Wallace Carothers Invented Nylon (U.S. Patent No. 2,130,523). U.S. Patent and Trademark Office. https://patentbrief.org/patent/us/2130523/nylon-polyamide-carothers

Auto-generated from the patent record. Double-check author order and the issue date against the official USPTO document before submitting.

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Common Questions

Frequently Asked Questions

What does How Wallace Carothers Invented Nylon cover?

The foundational 1935 patent for synthetic linear polyamides, the chemical process that created the material we now call nylon.

Who owns patent US 2130523?

EI Du Pont de Nemours and Co owns this patent, granted in 1938.

When does this patent expire?

This patent has expired and is now in the public domain — anyone can use the invention freely.

What is patent US 2130523 cited by?

This patent has been cited by 299 later patents that build on its ideas.

What problem does this patent solve?

This patent marks the birth of the synthetic fiber industry. It allowed DuPont to mass-produce nylon, which became a critical material for everything from hosiery to parachutes during World War II.

What does this patent NOT cover?

Does not cover non-linear or branched polyamide structures.

Same assignee

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Last reviewed: June 13, 2026 · PatentBrief is not a law firm and this is not legal advice.