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How Lithium-Ion Battery Cathodes Are Made

A foundational 1982 method for creating the materials used in rechargeable lithium-ion batteries by removing ions at low temperatures.

Granted 1982ExpiredExpired 2001Owned by IndividualInvented by Koichi Mizushima, John B. Goodenough

Original patent title: “Fast ion conductors

Plain-English explanation by SahiLast reviewed · June 13, 2026

A foundational 1982 method for creating the materials used in rechargeable lithium-ion batteries by removing ions at low temperatures. Granted to Individual in 1982 with 4 claims and 41 forward citations, and it is now in the public domain.

Coverage

What does this patent actually cover?

This patent describes a chemical process to create stable materials for battery electrodes, specifically those with a layered structure like alpha-NaCrO2. The inventors discovered that you cannot create these materials using high-heat methods because the structure becomes unstable. Instead, the patent claimsclaimsThe numbered statements at the end of a patent that legally define what the inventor owns.Read more → a method of electrochemical extraction, where you pull positive ions (like Lithium) out of a starting compound at low temperatures to create the final, active electrode material.

The gap

What does this patent NOT cover?

  • Does not cover the physical assembly of a complete battery cell.
  • Does not cover high-temperature manufacturing processes for these materials.
  • Does not cover the use of materials that do not follow the specific A x M y O 2 layered structure.
  • Does not cover the specific electrolyte compositions used in the battery.

These exclusions are unique to PatentBrief — derived from the actual claim language, not patent-office boilerplate.

Key facts

Patent numberUS 4357215
StatusExpired
FieldConsumer Electronics
AssigneeIndividual
InventorsKoichi Mizushima, John B. Goodenough
Filed1981
Granted1982
Expires2001 (expired)
Claims4
Times cited41
LitigationNone on record
Value · $13K$40KMinimal

What made this novel

The inventors realized that high-temperature synthesis destroyed the material's stability, so they used electrochemical extraction at low temperatures to 'strip' ions out, creating a stable, high-energy-density structure that shouldn't have existed otherwise.

The Patent Drawing

Representative patent drawing for Fast ion conductors (US 4357215)
Representative figure · US 4357215All figures on Google Patents →
Fast ion conductors(Primary claim)consumer electronicsenergymaterials

Schematic visualization of the patent's claim structure. Hand-drawn diagrams in progress for each landmark patent.

Where you've seen this

Real-world examples

01

Lithium cobalt oxide (LiCoO2) cathodes in smartphones

02

Rechargeable battery packs for electric vehicles

03

Portable power banks

Why it matters

The bigger picture

This patent is a cornerstone of modern portable electronics. It provided the chemical blueprint for the cathode materials found in almost every lithium-ion battery used in smartphones, laptops, and electric vehicles today. John B. Goodenough later received a Nobel Prize for this work, which enabled the transition from disposable batteries to rechargeable ones.

Filed

April 30, 1981

Granted

November 2, 1982

Market context

Who's building on this

Companies in this space

Major battery manufacturers like Panasonic, LG Energy Solution, and CATL build upon these fundamental material science principles. The technology is now industry-standard, and research continues into optimizing these layered oxides for higher energy density.

Market impact

This patent effectively enabled the entire lithium-ion battery industry. By defining a viable way to produce stable cathode materials, it allowed for the miniaturization of power sources, which directly led to the development of the modern mobile computing and electric vehicle markets.

Claim 1 — Plain English

What this patent covers

This patent describes a chemical process to create stable materials for battery electrodes, specifically those with a layered structure like alpha-NaCrO2. The inventors discovered that you cannot create these materials using high-heat methods because the structure becomes unstable. Instead, the patent claims a method of electrochemical extraction, where you pull positive ions (like Lithium) out of a starting compound at low temperatures to create the final, active electrode material.

The clever bit

The inventors realized that high-temperature synthesis destroyed the material's stability, so they used electrochemical extraction at low temperatures to 'strip' ions out, creating a stable, high-energy-density structure that shouldn't have existed otherwise.

What it does not cover

  • Does not cover the physical assembly of a complete battery cell.
  • Does not cover high-temperature manufacturing processes for these materials.
  • Does not cover the use of materials that do not follow the specific A x M y O 2 layered structure.
  • Does not cover the specific electrolyte compositions used in the battery.

Patent timeline

Filing

Application submitted to the patent office

Publication

Application published, typically 18 months after filing

Grant

Patent officially issued

Expiration

Patent enters public domain

This patent is in the public domain

See the Freedom to Build guide — what is free to use, what is not, and how to cite this patent.

View guide →

PatentBrief Score

Impact Score

Early stage

Citation count

32/40

Moderately cited

Claim breadth

3/20

Narrow claimsclaimsThe numbered statements at the end of a patent that legally define what the inventor owns.Read more →

Recency

0/20

Older than 20 years

Assignee scale

0/20

Independent or smaller assigneeassigneeThe entity that owns the patent — usually the inventor's employer or a company.Read more →

PatentBrief Impact Score — based on citation count, claim breadth, recency, and assignee scale. Not a legal assessment.

Heuristic Value Estimate

What this patent might be worth

Minimal

$13K$40K

Midpoint $25K · expired or expiring · industry ×1.4

Adjust inputs →

Heuristic only — blends forward/backward citation counts, claim scope, time remaining, litigation history, and CPC-derived industry baseline. Real valuations need a professional appraisal.

Patent Claims

0 independent claims · 1 dependent

Claims are the legal boundaries of the patent. An independent claim stands alone. A dependent claim adds limitations to its parent, narrowing — but not broadening — the scope.

The original legal language

Original claims

4 claims as filed with the patent office.

Concepts involved

ClaimPrior artNon-obviousnessNoveltySpecificationAssigneePatent term

Citations

Patent lineage

Cites earlier patents

3

earlier patents this invention cites as foundations

View prior art →

Cited by later patents

41

later patents that build on this invention

View patents →

Cite this patent

Mizushima, K., & Goodenough, J. B. (1982). How Lithium-Ion Battery Cathodes Are Made (U.S. Patent No. 4,357,215). U.S. Patent and Trademark Office. https://patentbrief.org/patent/us/4357215/lithium-ion-cathode-goodenough

Auto-generated from the patent record. Double-check author order and the issue date against the official USPTO document before submitting.

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Common Questions

Frequently Asked Questions

What does How Lithium-Ion Battery Cathodes Are Made cover?

A foundational 1982 method for creating the materials used in rechargeable lithium-ion batteries by removing ions at low temperatures.

Who owns patent US 4357215?

Individual owns this patent, granted in 1982.

When does this patent expire?

This patent has expired and is now in the public domain — anyone can use the invention freely.

What is patent US 4357215 cited by?

This patent has been cited by 41 later patents that build on its ideas.

What problem does this patent solve?

This patent is a cornerstone of modern portable electronics. It provided the chemical blueprint for the cathode materials found in almost every lithium-ion battery used in smartphones, laptops, and electric vehicles today. John B. Goodenough later received a Nobel Prize for this work, which enabled the transition from disposable batteries to rechargeable ones.

What does this patent NOT cover?

Does not cover the physical assembly of a complete battery cell.

Same assignee

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Last reviewed: June 13, 2026 · PatentBrief is not a law firm and this is not legal advice.