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How a Special Reactor Makes Methane Fuel Without Constant Electricity

This patent describes a method for a Solid Oxide Electrolyser Cell (SOEC) reactor to produce methane, even when electricity is scarce, by switching from electrolysis to a heat-generating chemical reaction.

Granted 2018ActiveExpires 2034Owned by Commissariat a lEnergie Atomique et aux Energies Alternatives CEAInvented by Magali REYTIER, Guilhem Roux, Marie PETITJEAN

Original patent title: “Method for operating an SOEC-type stack reactor for producing methane in the absence of available electricity

Plain-English explanation by SahiLast reviewed · September 15, 2026

This patent describes a method for a Solid Oxide Electrolyser Cell (SOEC) reactor to produce methane, even when electricity is scarce, by switching from electrolysis to a heat-generating chemical reaction. Granted to Commissariat a lEnergie Atomique et aux Energies Alternatives CEA in 2018 with 17 claims, and it is expected to expire in 2034.

Coverage

What does this patent actually cover?

This patent details a two-step process for operating a Solid Oxide Electrolyser Cell (SOEC) stack reactor, where the cathodes are made of catalytic material. First, when electricity is available (step a/ of claimclaimA numbered sentence at the end of a patent that legally defines what the inventor owns. The most important section.Read more → 1), the reactor performs high-temperature electrolysis, splitting steam or a mix of steam and carbon dioxide to produce hydrogen or a mix of hydrogen and carbon monoxide. Second, when the electricity supply becomes insufficient for electrolysis (step b/ of claim 1), the reactor switches modes. It is then supplied with a mixture of hydrogen and carbon monoxide (synthesis gas) or hydrogen and carbon dioxide. This mixture undergoes a methanation reaction at the same cathodes, producing methane. This methanation reaction is exothermic, meaning it releases heat, which helps keep the reactor at its operating temperature without needing continuous electricity. For example, a reactor powered by solar panels could produce hydrogen during the day and then use that hydrogen to make methane at night, keeping itself warm.

The gap

What does this patent NOT cover?

  • Does not cover methanation processes that do not occur within an SOEC-type stack reactor where the cathodes are specifically made of methanation catalyst material(s).
  • Does not cover systems where the reactor is only used for electrolysis or only for methanation, without the ability to switch between these two modes based on electricity availability.
  • Does not cover methanation reactions that are not performed by 'heterogeneous catalysis' at the cathode.
  • Does not cover producing methane when electricity is fully available for electrolysis, as the patent specifically addresses operating when the electric current is 'insufficient' for electrolysis.
  • Does not cover reactors that lack the specific arrangement of electrical and fluid interconnectors between adjacent elemental cells as described in claimclaimA numbered sentence at the end of a patent that legally defines what the inventor owns. The most important section.Read more → 1.

These exclusions are unique to PatentBrief — derived from the actual claim language, not patent-office boilerplate.

Key facts

Patent numberUS 10145018
StatusActive
FieldEnergy & Clean Tech
AssigneeCommissariat a lEnergie Atomique et aux Energies Alternatives CEA
InventorsMagali REYTIER, Guilhem Roux, Marie PETITJEAN
Filed2014
Granted2018
Expires2034
Claims17
Times cited0
LitigationNone on record
Value · $39K$125KMinimal

What made this novel

The core innovation is using the *same* SOEC reactor, with its catalyst-embedded cathodes, to perform *both* high-temperature electrolysis (when electricity is available) and exothermic methanation (when electricity is not), using the heat from the methanation reaction to keep the reactor at operating temperature.

The Patent Drawing

Representative patent drawing for Method for operating an SOEC-type stack reactor for producing methane in the absence of available electricity (US 10145018)
Representative figure · US 10145018All figures on Google Patents →
Method for operating an SOEC-t…(Primary claim)energychemical manufacturingmaterialstelecommunications

Schematic visualization of the patent's claim structure. Hand-drawn diagrams in progress for each landmark patent.

Where you've seen this

Real-world examples

01

Power-to-gas energy storage systems

02

Synthetic natural gas production from renewable electricity

03

Industrial processes for carbon dioxide utilization

04

Chemical energy storage for grid balancing

Why it matters

The bigger picture

This patent addresses a significant challenge in renewable energy: its intermittent nature. By allowing a single reactor to both produce hydrogen/syngas when electricity is abundant and then convert it to methane when electricity is scarce, it offers a way to store excess renewable energy in a chemical form. Methane is easier to store and transport than hydrogen and can be integrated into existing gas infrastructure, making renewable energy more reliable and usable on demand.

Filed

November 19, 2014

Granted

December 4, 2018

Market context

Who's building on this

Companies in this space

The Commissariat à l'Énergie Atomique et aux Énergies Alternatives (CEA), the original assigneeassigneeThe entity that owns the patent — usually the inventor's employer or a company.Read more →, remains a key player in this field, conducting extensive research in energy technologies. Other entities in the 'power-to-gas' sector, such as Siemens Energy and Sunfire, are actively developing and commercializing related technologies for converting renewable electricity into synthetic fuels like methane. Academic institutions and startups globally are also exploring advanced reactor designs for efficient energy conversion and storage.

Market impact

This technology contributes to the growing 'power-to-gas' market, enabling the storage of intermittent renewable electricity, such as from solar or wind, as chemical energy in the form of methane. This can help stabilize electricity grids by providing a flexible energy buffer and offers a pathway for decarbonizing sectors difficult to electrify, like heavy industry and transportation, by leveraging existing gas infrastructure. It supports the transition towards a more sustainable and resilient energy system by making renewable energy more dispatchable and versatile.

Claim 1 — Plain English

What this patent covers

This patent details a two-step process for operating a Solid Oxide Electrolyser Cell (SOEC) stack reactor, where the cathodes are made of catalytic material. First, when electricity is available (step a/ of claim 1), the reactor performs high-temperature electrolysis, splitting steam or a mix of steam and carbon dioxide to produce hydrogen or a mix of hydrogen and carbon monoxide. Second, when the electricity supply becomes insufficient for electrolysis (step b/ of claim 1), the reactor switches modes. It is then supplied with a mixture of hydrogen and carbon monoxide (synthesis gas) or hydrogen and carbon dioxide. This mixture undergoes a methanation reaction at the same cathodes, producing methane. This methanation reaction is exothermic, meaning it releases heat, which helps keep the reactor at its operating temperature without needing continuous electricity. For example, a reactor powered by solar panels could produce hydrogen during the day and then use that hydrogen to make methane at night, keeping itself warm.

The clever bit

The core innovation is using the *same* SOEC reactor, with its catalyst-embedded cathodes, to perform *both* high-temperature electrolysis (when electricity is available) and exothermic methanation (when electricity is not), using the heat from the methanation reaction to keep the reactor at operating temperature.

What it does not cover

  • Does not cover methanation processes that do not occur within an SOEC-type stack reactor where the cathodes are specifically made of methanation catalyst material(s).
  • Does not cover systems where the reactor is only used for electrolysis or only for methanation, without the ability to switch between these two modes based on electricity availability.
  • Does not cover methanation reactions that are not performed by 'heterogeneous catalysis' at the cathode.
  • Does not cover producing methane when electricity is fully available for electrolysis, as the patent specifically addresses operating when the electric current is 'insufficient' for electrolysis.
  • Does not cover reactors that lack the specific arrangement of electrical and fluid interconnectors between adjacent elemental cells as described in claim 1.

Patent timeline

Filing

Application submitted to the patent office

Publication

Application published, typically 18 months after filing

Grant

Patent officially issued

Expiration

Patent enters public domain

PatentBrief Score

Impact Score

Early stage

Citation count

0/40

No citations yet

Claim breadth

11/20

Broad claimsclaimsThe numbered statements at the end of a patent that legally define what the inventor owns.Read more →

Recency

10/20

Granted 5–10 years ago

Assignee scale

0/20

Independent or smaller assigneeassigneeThe entity that owns the patent — usually the inventor's employer or a company.Read more →

PatentBrief Impact Score — based on citation count, claim breadth, recency, and assignee scale. Not a legal assessment.

Heuristic Value Estimate

What this patent might be worth

Minimal

$39K$125K

Midpoint $78K · 8.2 yr remaining · industry ×2.4

Adjust inputs →

Heuristic only — blends forward/backward citation counts, claim scope, time remaining, litigation history, and CPC-derived industry baseline. Real valuations need a professional appraisal.

Claim text not yet imported for this patent

The original legal language

Original claims

17 claims as filed with the patent office.

Concepts involved

ClaimPrior artNon-obviousnessNoveltySpecificationAssigneePatent term

Citations

Patent lineage

Cites earlier patents

5

earlier patents this invention cites as foundations

View prior art →

Cite this patent

REYTIER, M., Roux, G., & PETITJEAN, M. (2018). How a Special Reactor Makes Methane Fuel Without Constant Electricity (U.S. Patent No. 10,145,018). U.S. Patent and Trademark Office. https://patentbrief.org/patent/us/10145018/method-for-operating-an-soec-type-stack-reactor-for-producing-methane-in-the-abs

Auto-generated from the patent record. Double-check author order and the issue date against the official USPTO document before submitting.

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Common Questions

Frequently Asked Questions

What does How a Special Reactor Makes Methane Fuel Without Constant Electricity cover?

This patent describes a method for a Solid Oxide Electrolyser Cell (SOEC) reactor to produce methane, even when electricity is scarce, by switching from electrolysis to a heat-generating chemical reaction.

Who owns patent US 10145018?

Commissariat a lEnergie Atomique et aux Energies Alternatives CEA owns this patent, granted in 2018.

When does this patent expire?

This patent is expected to expire on November 19, 2034, when the invention enters the public domain.

What problem does this patent solve?

This patent addresses a significant challenge in renewable energy: its intermittent nature. By allowing a single reactor to both produce hydrogen/syngas when electricity is abundant and then convert it to methane when electricity is scarce, it offers a way to store excess renewable energy in a chemical form. Methane is easier to store and transport than hydrogen and can be integrated into existing gas infrastructure, making renewable energy more reliable and usable on demand.

What does this patent NOT cover?

Does not cover methanation processes that do not occur within an SOEC-type stack reactor where the cathodes are specifically made of methanation catalyst material(s).

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Last reviewed: September 15, 2026 · PatentBrief is not a law firm and this is not legal advice.