Skip to content
PatentBrief

Solid-State Cooling & Caloric Materials Patents

Electrocaloric Material Patents

Electrocaloric materials (large temperature change, high breakdown — the heart) and the regenerator that cascades the small per-cycle effect into useful cooling — for refrigerant-free solid-state cooling, entering first in electronics and niche applications as refrigerants phase down; electrocaloric-material patent landscape for solid-state-cooling founders.

FAQ

Who holds electrocaloric material patents and why is solid-state cooling promising?

Electrocaloric material patents cover material/effect innovations; device/regenerator innovations; system/efficiency innovations; and application/integration innovations — with IP held by cooling, materials, and electronics companies and research organizations (in a field of solid-state caloric cooling). WHY ELECTROCALORIC: 'ELECTROCALORIC' materials cool things using ELECTRICITY and a SOLID material — no refrigerant gases, no compressor; the ELECTROCALORIC EFFECT is the property that certain materials (ferroelectric POLYMERS and CERAMICS) HEAT UP slightly when an electric FIELD is applied (their molecular dipoles ALIGN, lowering entropy) and COOL DOWN when the field is removed; by repeatedly applying and removing the field while moving heat away during the hot phase, an electrocaloric device acts as a SOLID-STATE HEAT PUMP — pumping heat from cold to hot to refrigerate or air-condition, driven by electricity, with NO greenhouse-gas refrigerants and NO moving compressor; this is attractive as a CLEAN alternative to VAPOR-COMPRESSION cooling: the refrigerants used today are potent GREENHOUSE GASES (being phased down), and solid-state cooling could be quiet, compact, efficient, and refrigerant-free; the CATCH: a single electrocaloric cycle only changes temperature by a FEW DEGREES, so to get useful cooling (tens of degrees) you need REGENERATION (cascading the small temperature changes) — and the materials, devices, and efficiency are still maturing; the brutal CHALLENGES: the MATERIAL/EFFECT (electrocaloric materials with a LARGE temperature change, high BREAKDOWN strength, and reliability — the HEART), the DEVICE/REGENERATOR (turning the small per-cycle effect into useful cooling via REGENERATION/cascading and heat transfer — the central engineering challenge), the SYSTEM/EFFICIENCY (achieving competitive efficiency (COP) and lifetime), and the APPLICATION/INTEGRATION (where solid-state cooling WINS — electronics, niche, then mainstream); the make-or-break IP AREAS: the MATERIAL/effect, the DEVICE/regenerator, the SYSTEM/efficiency, and the application/integration; the HARD problems: the MATERIAL, DEVICE, SYSTEM, and APPLICATION. MAJOR PLAYERS: cooling, materials, and electronics companies and research labs. Material/effect, device/regenerator, system/efficiency, and application/integration are the core electrocaloric patent domains — and material, device, system, and application are the open whitespace. (Note: ELECTROCALORIC materials cool using ELECTRICITY + a solid material (no refrigerant gases/compressor) — the ELECTROCALORIC EFFECT (ferroelectric polymers/ceramics HEAT UP when an electric FIELD is applied + COOL DOWN when removed); cycling the field while moving heat makes a SOLID-STATE HEAT PUMP — a clean alternative to vapor-compression (whose refrigerants are potent greenhouse gases); the catch: one cycle changes temperature only a few degrees → useful cooling needs REGENERATION (cascading) + the materials/devices/efficiency are maturing; brutal challenges in the MATERIAL/EFFECT (large temperature change — the heart), the DEVICE/REGENERATOR (the central engineering challenge), the SYSTEM/EFFICIENCY, and the APPLICATION; materials/device IP §101-resilient.)

What material/effect and device/regenerator innovations are patentable?

Material/effect innovations; device/regenerator innovations; electrocaloric-material innovations; and regenerator innovations represent core electrocaloric patent domains — and the material/effect (the heart) and the device/regenerator (turning the small effect into useful cooling) are the foundational, high-value, §101-resilient capabilities. MATERIAL / EFFECT PATENTS: the HEART — electrocaloric MATERIALS (the materials with a strong electrocaloric effect — ferroelectric POLYMERS (PVDF-based, like P(VDF-TrFE) terpolymers — large effect, flexible, good for thin films), CERAMICS (PZT, relaxor ferroelectrics like PMN-PT — large effect but rigid), and THIN FILMS (high fields → large effect)), LARGE ELECTROCALORIC TEMPERATURE CHANGE (the key metric — a bigger per-cycle temperature change means more cooling), BREAKDOWN STRENGTH (the material must withstand the high electric fields needed for a large effect without electrical breakdown — a key limit), and RELIABILITY/FATIGUE (surviving millions of field cycles without degrading); material methods are core, high-value, DISTINCTIVE IP, §101-resilient (the electrocaloric MATERIALS (polymers/ceramics/thin-films, large temperature change, breakdown strength, fatigue) — as composition-of-matter — are the central, most contested, defensible IP, since the material's electrocaloric effect, field tolerance, and durability determine whether the cooling is useful). DEVICE / REGENERATOR PATENTS: the ENGINEERING — the REGENERATOR/CASCADE (THE central engineering challenge — since one cycle only changes temperature a few degrees, the device must REGENERATE (cascade/stack the small changes, shuttling heat through a stack of material so the temperature span builds up to tens of degrees) — the regenerator design is what turns a small effect into useful cooling), HEAT-TRANSFER/FLUID design (moving heat in and out of the material efficiently each cycle — via a fluid or solid-state heat switch — a key efficiency factor), DEVICE ARCHITECTURE (how the material, electrodes, and heat-transfer are arranged), and FIELD APPLICATION (applying/removing the high field efficiently); device methods are core, high-value, DISTINCTIVE IP, §101-resilient (the REGENERATOR/cascade, heat-transfer/fluid design, and device architecture are the central, most contested, defensible IP, since regeneration is exactly what turns the small per-cycle electrocaloric effect into a useful temperature span — the make-or-break engineering). ELECTROCALORIC-MATERIAL PATENTS: large-effect high-breakdown durable electrocaloric materials; electrocaloric-material methods are high-value IP, §101-resilient (the material is the heart — effect size/durability decisive). REGENERATOR PATENTS: regenerator/cascade designs building a large temperature span; regenerator methods are high-value IP, §101-resilient (regeneration turns the small effect into useful cooling — the central engineering). Material/effect, device/regenerator, electrocaloric-material, and regenerator are the highest-value core IP because the material (effect size/durability) and the regenerator (cascading the small effect) are exactly what make electrocaloric cooling useful.

What system/efficiency and application/integration innovations are patentable?

System/efficiency innovations; application/integration innovations; solid-state-cooling innovations; and refrigerant-free-cooling innovations represent additional electrocaloric patent domains — and the system/efficiency (competitive performance) and the application/integration (where solid-state cooling wins) turn the device into a viable, valuable cooling product. SYSTEM / EFFICIENCY PATENTS: the VIABILITY — EFFICIENCY/COP (the coefficient of performance — to compete with vapor-compression, electrocaloric cooling must be EFFICIENT — so maximizing COP via material, regeneration, and heat-transfer is central), POWER/COOLING DENSITY (cooling power per volume/mass — for compact devices), LIFETIME/CYCLING (surviving millions/billions of field cycles — material and device durability), and the ELECTRONICS/DRIVE (the high-voltage electronics that apply the field efficiently — recovering the electrical energy each cycle is important for efficiency); system methods are core, high-value, DISTINCTIVE IP, §101-resilient (EFFICIENCY/COP, power density, LIFETIME/cycling, and the energy-recovering drive electronics are core, contested, defensible IP, since competitive efficiency and lifetime are the make-or-break for adoption). APPLICATION / INTEGRATION PATENTS: the USE — ELECTRONICS/CHIP COOLING (a strong near-term niche — compact, quiet, solid-state cooling for hot chips/electronics, where vapor-compression doesn't fit and the value of compact precise cooling is high), NICHE/COMPACT cooling (portable coolers, medical, wine fridges, spot cooling — where compactness/quiet/refrigerant-free matters), REFRIGERATION/AIR-CONDITIONING (the long-term mainstream prize — but must beat mature, cheap vapor-compression), and INTEGRATION vs vapor-compression (where electrocaloric's no-refrigerant, quiet, compact advantages justify it); application methods are core, high-value IP, §101-resilient when tied to the device (ELECTRONICS/chip cooling, niche/compact cooling, and integration are core value, since solid-state cooling wins first in niches (electronics, compact, refrigerant-sensitive) before mainstream, and choosing the right entry application is the make-or-break). SOLID-STATE-COOLING PATENTS: electrocaloric solid-state heat pumps/coolers; solid-state-cooling methods are high-value IP, §101-resilient (solid-state, no-moving-parts, refrigerant-free cooling is the core proposition). REFRIGERANT-FREE-COOLING PATENTS: cooling without greenhouse-gas refrigerants; refrigerant-free-cooling methods are high-value IP, §101-resilient (refrigerant-free is the key environmental advantage as refrigerants are phased down). System/efficiency, application/integration, solid-state-cooling, and refrigerant-free-cooling are the highest-value IP because competitive efficiency and the right entry application (electronics/niche) turn electrocaloric devices into viable, refrigerant-free coolers.

What IP strategy should electrocaloric startup founders use?

Electrocaloric startup IP strategy must navigate the material-effect-and-regenerator-are-the-two-central-make-or-breaks (the two make-or-breaks are (1) the MATERIAL's electrocaloric EFFECT (a large temperature change, high breakdown, durable) and (2) the REGENERATOR/device that CASCADES the small per-cycle effect into a useful temperature span — so material and regenerator IP are the most distinctive and decisive, since a great material with a poor regenerator (or vice versa) doesn't cool usefully), the §101-resilient-materials-and-device-are-the-strength (electrocaloric IP is materials/device/thermal IP — composition-of-matter MATERIALS, devices, and regenerators are PATENTABLE and strongly §101-RESILIENT — so material, device, system, and application claims are strong (a key advantage)), the refrigerant-phase-down-is-the-big-tailwind (HFC refrigerants (potent greenhouse gases) are being PHASED DOWN globally (Kigali Amendment, regulations) — creating a strong tailwind for REFRIGERANT-FREE cooling alternatives — so a startup should leverage this regulatory/ESG driver, since the refrigerant problem is real and growing), the electronics-and-niche-cooling-are-the-realistic-entry-applications (electrocaloric cooling should enter first where it WINS — ELECTRONICS/chip cooling (compact, quiet, precise, where vapor-compression doesn't fit) and NICHE/compact cooling — NOT head-on against cheap mature air-conditioning — so a startup should target electronics/niche entry, where the value of compact solid-state cooling is highest and the bar is achievable), the efficiency-vs-vapor-compression-be-realistic (mature VAPOR-COMPRESSION cooling is cheap and efficient — so be VERY realistic: electrocaloric must reach competitive EFFICIENCY (COP) and lifetime to win mainstream cooling, which is hard — so compete first on its unique advantages (no refrigerant, compact, quiet, precise), not raw efficiency), the regeneration-and-heat-transfer-are-the-hard-engineering (REGENERATION (cascading the small effect) and the per-cycle HEAT TRANSFER (in/out of the material fast and efficiently) are the hard engineering — so regenerator/heat-transfer IP is high-value, since it determines the achievable temperature span and efficiency), the lifetime-and-fatigue-are-critical-reliability-make-or-breaks (the material and device must survive MILLIONS-billions of field cycles without degrading (electrical fatigue, breakdown) — so durability/fatigue IP is a critical reliability make-or-break, since a cooler that wears out fast is useless), the energy-recovery-in-the-drive-electronics-boosts-efficiency (applying/removing high electric fields each cycle uses energy — RECOVERING that electrical energy (the field energy) each cycle is important for system efficiency — so energy-recovering drive-electronics IP is high-value), the competing-caloric-technologies-context (electrocaloric competes with other CALORIC cooling (MAGNETOcaloric (magnetic refrigeration), ELASTOcaloric (mechanical), BAROcaloric) and thermoelectric — so a startup should understand electrocaloric's relative advantages (electric drive, polymer flexibility) and position accordingly), the incumbent-and-academia-and-FTO (cooling/HVAC majors exploring solid-state cooling, electronics-cooling companies, plus extensive ACADEMIC electrocaloric research (much published) have IP — so a startup needs a genuinely novel material/regenerator/system/application edge, careful FTO, and awareness of deep academic prior art), the demonstrated-temperature-span-COP-and-lifetime-decide (electrocaloric devices are proven by demonstrated TEMPERATURE SPAN, COOLING POWER, EFFICIENCY (COP), and LIFETIME/cycling — so demonstrated, device-validated performance is decisive, far more than patents (and the field is still early)), the be-realistic-the-technology-is-early-stage (electrocaloric cooling is still EARLY-STAGE (small devices, maturing materials/efficiency) — so be VERY realistic about the development timeline and the gap to commercial cooling), and a landscape where material, device, system, and application are the durable assets; understand that material + regenerator are the two make-or-breaks and electronics/niche is the entry, so the durable startup IP is in the electrocaloric material, the regenerator/device, efficiency/durability, and electronics/niche applications — with a large-effect durable material, an efficient regenerator, and a strong niche application often the real moat, and that §101-resilient materials IP, demonstrated span/COP/lifetime, application fit, and FTO matter as much as patents; identify whitespace in materials, regenerators, efficiency, and electronics/niche applications. ELECTROCALORIC STARTUP IP STRATEGY: MATERIAL/EFFECT, DEVICE/REGENERATOR, SYSTEM/EFFICIENCY, AND APPLICATION/INTEGRATION ARE THE IP: patent materials, devices/regenerators, systems, and applications — materials/device claims (§101-resilient); MATERIAL-EFFECT-AND-REGENERATOR-ARE-THE-TWO-CENTRAL-MAKE-OR-BREAKS: (1) the MATERIAL's electrocaloric EFFECT (large temperature change/high breakdown/durable) + (2) the REGENERATOR/device CASCADING the small per-cycle effect into a useful span — material + regenerator IP the most distinctive decisive (a great material with a poor regenerator doesn't cool usefully); §101-RESILIENT-MATERIALS-AND-DEVICE-ARE-THE-STRENGTH: materials/device/thermal IP — composition-of-matter MATERIALS/devices/regenerators PATENTABLE + strongly §101-RESILIENT (material/device/system/application claims strong — a key advantage); REFRIGERANT-PHASE-DOWN-IS-THE-BIG-TAILWIND: HFC refrigerants (potent greenhouse gases) being PHASED DOWN globally (Kigali/regulations) → strong tailwind for REFRIGERANT-FREE alternatives — leverage this regulatory/ESG driver (the refrigerant problem real + growing); ELECTRONICS-AND-NICHE-COOLING-ARE-THE-REALISTIC-ENTRY-APPLICATIONS: enter first where it WINS — ELECTRONICS/chip cooling (compact/quiet/precise where vapor-compression doesn't fit) + NICHE/compact — NOT head-on vs cheap mature air-conditioning — target electronics/niche entry (value of compact solid-state cooling highest + the bar achievable); EFFICIENCY-VS-VAPOR-COMPRESSION-BE-REALISTIC: mature VAPOR-COMPRESSION cheap + efficient — be VERY realistic: must reach competitive EFFICIENCY (COP) + lifetime to win mainstream (hard) — compete first on unique advantages (no refrigerant/compact/quiet/precise) not raw efficiency; REGENERATION-AND-HEAT-TRANSFER-ARE-THE-HARD-ENGINEERING: REGENERATION (cascading the small effect) + per-cycle HEAT TRANSFER (in/out fast + efficient) the hard engineering — regenerator/heat-transfer IP high-value (determines the temperature span + efficiency); LIFETIME-AND-FATIGUE-ARE-CRITICAL-RELIABILITY-MAKE-OR-BREAKS: material + device must survive MILLIONS-billions of field cycles without degrading (fatigue/breakdown) — durability/fatigue IP a critical reliability make-or-break; ENERGY-RECOVERY-IN-THE-DRIVE-ELECTRONICS-BOOSTS-EFFICIENCY: applying/removing high fields each cycle uses energy — RECOVERING the field energy each cycle important for efficiency — energy-recovering drive-electronics IP high-value; COMPETING-CALORIC-TECHNOLOGIES-CONTEXT: competes with MAGNETOcaloric/ELASTOcaloric/BAROcaloric + thermoelectric — understand electrocaloric's relative advantages (electric drive/polymer flexibility) + position accordingly; INCUMBENT-AND-ACADEMIA-AND-FTO: cooling/HVAC majors + electronics-cooling companies + extensive ACADEMIC electrocaloric research (much published) with IP — need a genuinely novel material/regenerator/system/application edge + careful FTO + deep academic prior art; DEMONSTRATED-TEMPERATURE-SPAN-COP-AND-LIFETIME-DECIDE: proven by TEMPERATURE SPAN/COOLING POWER/EFFICIENCY-COP/LIFETIME-cycling — demonstrated device-validated performance decisive (far more than patents — the field early); BE-REALISTIC-THE-TECHNOLOGY-IS-EARLY-STAGE: still EARLY-STAGE (small devices/maturing materials-efficiency) — be VERY realistic about the timeline + the gap to commercial cooling; §101-RESILIENT-MATERIALS/SPAN-COP-LIFETIME/APPLICATION-FIT/FTO MATTER AS MUCH AS PATENTS: §101-resilient materials IP, demonstrated span/COP/lifetime, application fit, and FTO drive value; WHEN TO PATENT: NOVEL MATERIAL/REGENERATOR/SYSTEM/APPLICATION WITH DATA: file once it shows data (material temperature-change/breakdown/fatigue + regenerator temperature-span + COP/lifetime + application) — materials/device claims (materials as composition-of-matter); demonstrated temperature span, cooling power, COP, and lifetime are the critical electrocaloric IP metrics; KEY FTO CHECKLIST: cooling/HVAC majors + electronics-cooling companies + academia (much published); material/effect (electrocaloric MATERIALS-ferroelectric POLYMERS-PVDF-P-VDF-TrFE/CERAMICS-PZT-relaxor-PMN-PT/thin films/large electrocaloric temperature change/breakdown strength/reliability-fatigue — §101-resilient, composition-of-matter, the heart); device/regenerator (REGENERATOR-cascade-build-temperature-span/heat-transfer-fluid design/device architecture/field application — §101-resilient, the central engineering); electrocaloric-material; regenerator (cascading the small effect); system/efficiency (EFFICIENCY-COP/power-cooling density/LIFETIME-cycling/energy-recovering drive electronics — §101-resilient, the viability); application/integration (ELECTRONICS-chip cooling/niche-compact cooling/refrigeration-AC/integration-vs-vapor-compression — tie to device); solid-state-cooling (the core proposition); refrigerant-free-cooling (the environmental advantage); material-effect + regenerator the two central make-or-breaks; §101-resilient materials + device the strength; refrigerant phase-down the big tailwind; electronics + niche cooling the realistic entry applications; efficiency-vs-vapor-compression be realistic; regeneration + heat-transfer the hard engineering; lifetime + fatigue critical reliability make-or-breaks; energy-recovery in the drive electronics boosts efficiency; competing caloric technologies context; incumbent + academia + FTO; demonstrated temperature-span + COP + lifetime decide; be realistic — the technology is early-stage.

Related Guides

Magnetic Refrigeration PatentsThermoelectric Generator PatentsPhase Change Material PatentsStartup IP Strategy