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PatentBrief

Innovation Timeline

Advanced Materials

Gore-Tex, carbon fiber, nanotubes, and the materials science patents that created entirely new industries.

Landmark patents

99

Total citations

13,134

Span

18442024

Milestones

20

1840s

1850s

1860s

1870s

1880s

1890s

1900s

1910s

1920s

1930s

US 1967861· 1931· EI Du Pont de Nemours and CoPublic domain

How DuPont Invented Neoprene Synthetic Rubber

A 1934 patent describing the chemical process to turn chlorobutadiene into a durable, oil-resistant synthetic rubber known as Neoprene.

7 citations

US 2133235· 1933· Owens Illinois Glass CoPublic domain

How Glass Fibers Are Spun for Insulation

A 1933 invention by Games Slayter that describes the process of melting glass and blasting it into fine, flexible fibers to create insulation.

22 citations

Milestone
US 2130523· 1935· EI Du Pont de Nemours and CoPublic domain

How Wallace Carothers Invented Nylon

The foundational 1935 patent for synthetic linear polyamides, the chemical process that created the material we now call nylon.

299 citations

Milestone
US 2297691· 1939· IndividualPublic domain

Chester Carlson's Original Xerography Patent

Chester Carlson's 1942 patent for xerography, the dry copying process that became the foundation for Xerox machines.

737 citations

US 2230654· 1939· KINETIC CHEMICALS IncPublic domain

The Discovery of Teflon

This 1941 patent describes the creation of polytetrafluoroethylene, a slippery, heat-resistant plastic discovered by accident that became known as Teflon.

74 citations

1940s

1950s

US 2682235· 1951· IndividualPublic domain

Buckminster Fuller's Geodesic Dome Building Design

A structural design for a spherical building made of interlocking triangular frames that distribute weight efficiently to create large, stable, and lightweight spaces.

120 citations

Milestone
US 2717437· 1952· Velcro SAPublic domain

How George de Mestral Invented Velcro

A 1952 patent describing the creation of a hook-and-loop fastener by weaving synthetic loops into fabric and cutting them to create tiny, grippy hooks.

299 citations

US 2768109· 1954· Eastman Kodak CoPublic domain

How Super Glue Bonds Acidic Surfaces Like Wood

A 1954 method for using alcohol to help super glue stick to acidic surfaces like wood, which normally prevent the glue from hardening properly.

23 citations

US 2911759· 1954· Pilkington Brothers LtdPublic domain

How the Float Glass Process Makes Perfectly Flat Window Panes

This 1954 patent describes the float glass process, a method for creating high-quality, perfectly flat glass by floating molten glass on a bath of liquid metal.

53 citations

US 2929804· 1955· EI Du Pont de Nemours and CoPublic domain

How Spandex Elastic Fibers Are Chemically Engineered

DuPont's 1960 patent for a stretchy, durable synthetic fiber made from segmented polymers, which became the foundation for modern Spandex.

71 citations

Milestone
US 3142599· 1959· Sealed Air CorpPublic domain

How Bubble Wrap Is Manufactured

A 1959 manufacturing process that creates cushioning material by trapping air between two layers of plastic film.

185 citations

1960s

Milestone
US 3220960· 1960· IndividualPublic domain

How Soft Contact Lenses Were Invented Using Hydrogels

This patent describes the chemical recipe for soft, water-absorbing plastic materials that form the basis of modern soft contact lenses.

228 citations

US 3322485· 1962· RCA CorpPublic domain

How Liquid Crystal Displays (LCDs) Were Invented

This 1962 patent describes the first practical way to use organic liquid crystals to create a display that scatters light when an electric current is applied.

90 citations

Milestone
US 3489148· 1966· Procter and Gamble CoPublic domain

How Disposable Diapers Keep Skin Dry Using Porous Plastic Sheets

A 1970 patent by Procter and Gamble describing a specialized plastic top layer for diapers that allows liquid to pass through while keeping the baby's skin feeling dry.

133 citations

US 3671542· 1969· EI Du Pont de Nemours and CoPublic domain

How Stephanie Kwolek Invented the Liquid Crystal Solution for Kevlar

A 1969 chemical discovery describing a specialized liquid mixture that allows for the creation of incredibly strong, high-performance synthetic fibers.

132 citations

1970s

Milestone
US 3691140· 1970· IndividualPublic domain

Sticky, Tiny Plastic Balls Made from Acrylates

This 1972 patent describes how to make tiny, sticky, and durable plastic balls (microspheres) using a specific mix of acrylate chemicals and a special water-based process.

382 citations

US 3711262· 1970· Corning Glass WorksPublic domain

How Corning Invented Modern Fiber Optic Cables

A 1970 method for creating glass fibers that carry light over long distances by layering glass inside a tube and drawing it into a thin, solid strand.

86 citations

Milestone
US 3946398· 1970· SILONICS IncPublic domain

How Piezoelectric Inkjet Printing Works

A 1970 patent describing how to print images by using electrical pulses to bend a tiny crystal plate, squeezing individual ink drops out of a nozzle on demand.

448 citations

Milestone
US 3733309· 1970· EI Du Pont de Nemours and CoPublic domain

How Plastic Soda Bottles Are Made Stronger Using Stretched Molecules

A 1970s invention that describes how to make lightweight, clear plastic bottles strong enough to hold carbonated drinks without exploding.

170 citations

US 3778335· 1971· Corning Glass WorksPublic domain

How Chemically Strengthened Glass Works

A 1971 Corning patent describing a specific chemical recipe for glass that can be made incredibly tough by swapping small atoms in its surface for larger ones.

52 citations

Milestone
US 3819587· 1971· EI Du Pont de Nemours and CoPublic domain

The Molecular Structure of Kevlar High-Strength Fiber

Stephanie Kwolek's 1971 patent for DuPont describing the molecular alignment and manufacturing of extremely strong, lightweight synthetic aramid fibers, which became famous as Kevlar.

141 citations

Milestone
US 3953566· 1973· WL Gore and Associates IncPublic domain

Making Strong, Porous PTFE: The Gore-Tex Process

This patent describes a specific process for rapidly stretching a highly crystalline form of PTFE plastic to create a strong, porous material with a unique internal structure, forming the basis for products like Gore-Tex.

1,364 citations

US 4009052· 1976· Exxon Research and Engineering CoPublic domain

Early Lithium-Ion Battery Design Using Chalcogenides

This 1977 patent describes an early rechargeable battery design using lithium as one electrode and titanium disulfide as the other, a key step towards modern lithium-ion technology.

93 citations

Milestone
US 4166152· 1977· Minnesota Mining and Manufacturing CoPublic domain

The Sticky Microscopic Beads Behind Post-it Notes

3M's 1977 patent on tiny, naturally sticky plastic beads that can stick to a surface, peel off easily without leaving residue, and be reused over and over again.

278 citations

Milestone
US 4235871· 1978· Individual

How to Encapsulate Active Materials in Lipid Bubbles Efficiently

This patent describes a method for trapping biologically active substances inside tiny, multi-layered fat bubbles called liposomes, using a specific water-in-oil emulsion and gel-forming process to improve how much material gets captured.

1,862 citations

Milestone
US 4267420· 1978· General Mills IncPublic domain

How Microwave Crisping Sleeves Work

General Mills' 1978 patent on using a thin, metal-coated plastic wrap that converts microwave energy into intense surface heat to crisp and brown food like Hot Pockets.

234 citations

1980s

US 4302518· 1980· IndividualPublic domain

How Lithium-Cobalt Battery Cathodes Were Invented

This 1981 patent details the chemistry behind the lithium-cobalt oxide cathodes that power almost every modern smartphone, laptop, and electric vehicle.

90 citations

Milestone
US 4356429· 1980· Eastman Kodak CoPublic domain

How Organic Diodes Make Light Using Special Molecules

Eastman Kodak's 1982 patent on creating light-emitting diodes (OLEDs) using organic materials, specifically a layer of porphyrinic compounds to help inject electrical charges.

1,031 citations

US 4357215· 1981· IndividualPublic domain

How Lithium-Ion Battery Cathodes Are Made

A foundational 1982 method for creating the materials used in rechargeable lithium-ion batteries by removing ions at low temperatures.

41 citations

Milestone
US 4575330· 1984· UVP IncPublic domain

How 3D Printers Build Objects Layer by Layer from Liquid

This patent describes the foundational method for 3D printing, where a machine builds a three-dimensional object layer by layer by hardening a liquid material with light or other energy.

1,094 citations

Milestone
US 4727064· 1985· US Department of Health and Human Services

How Special Sugars Make Medicines Dissolve Better

This patent describes how to make poorly water-soluble drugs dissolve and absorb better by mixing them with specially modified, non-crystalline sugar molecules called cyclodextrin derivatives.

341 citations

US 4810490· 1987· Carter Wallace Inc

How to Make Clear, Waterproof Sunscreen That Doesn't Feel Greasy

A 1989 patent for a transparent, water-resistant sunscreen formula that uses wood rosin to create a non-sticky, long-lasting protective film on the skin.

11 citations

Milestone
US 5121329· 1989· Stratasys IncPublic domain

How Machines Build 3D Objects Layer by Layer from Melting Plastic

This patent describes a method and machine for creating three-dimensional objects by precisely depositing melted material, layer by layer, from a movable nozzle onto a base.

793 citations

1990s

US 5272135· 1991· Chiron Ophthalmics Inc

Preventing Protein Damage with Extra Methionine

This 1993 patent describes how adding extra methionine to protein-based medicines can prevent them from degrading, especially in liquid or semi-solid forms.

63 citations

US 5401560· 1993· Norton CoPublic domain

How to Make Durable Non-Slip Surfaces Using Electron Beam Curing

A method for creating flexible, non-slip materials by bonding mineral grit to plastic sheets using a special radiation-cured glue that stays strong even when stretched.

25 citations

Milestone
US 6267958· 1996· Genentech Inc

Making High-Concentration Antibody Medicines Stable for Injection

Genentech's 2001 patent on a method to create stable, concentrated antibody medicines that can be easily reconstituted for injection, preventing degradation during freezing and storage.

878 citations

Milestone
US 5961804· 1997· Massachusetts Institute of TechnologyPublic domain

Tiny Capsules for Electronic Paper Displays

MIT's 1999 patent on a special ink made of tiny capsules that can change color when an electric field is applied, forming the basis for early e-readers.

508 citations

US 6033785· 1997· Central Glass Co LtdPublic domain

How Car Windows Use Special Coatings to Balance Privacy and Visibility

A patent for automotive glass that uses a specific combination of tinted glass and multi-layered coatings to keep the inside private while ensuring the driver can see out clearly.

7 citations

2000s

US 6793929· 2000· Beiersdorf AG

How to Make Stable, High-Water Content Skin Creams

A recipe for creating stable skin lotions that are mostly water but feel like rich, oily creams by using specific silicone emulsifiers and carefully balanced oils.

25 citations

US RE39497· 2001· Nektar Therapeutics

How to Store Fragile Biological Materials Without Refrigeration

A method for preserving unstable biological materials like proteins by trapping them in a solid, glass-like sugar or polymer matrix that prevents decay at room temperature.

11 citations

US 7833668· 2007· Bloom Energy

How Fuel Cells Reuse Exhaust Hydrogen for High Efficiency

This patent describes a fuel cell system that captures and recycles over 95% of the unused hydrogen from its exhaust stream using a special pump, significantly boosting efficiency.

29 citations

US 8156057· 2008· Knowmtech

How Nanoparticles Form Adaptive Neural Network Connections

This patent describes how to build and strengthen a physical neural network using tiny nanoparticles suspended in a liquid, where electric fields make the connections learn and adapt.

12 citations

US 8932024· 2008· Mitsubishi Heavy Industries

Wind Turbine Blades with Noise-Reducing Serrated Edges

This patent describes a wind turbine blade design that reduces noise by attaching a special serrated plate to its trailing edge, integrated directly into one of the blade's outer surfaces.

20 citations

US 8912428· 2008· Epir Technologies

Solar Cells Made of Stacking Layers with Different Energy Gaps

This patent describes a solar cell built by stacking multiple layers, each designed to capture a different part of the light spectrum for maximum energy conversion, achieving high efficiency.

2 citations

US 20110132770· 2009· Areva SA

Making Chemicals from Carbon Dioxide and Steam Using Electricity

This patent describes a process that uses electricity to split steam and then reacts the resulting hydrogen with carbon dioxide or carbon monoxide to create various carbon-based compounds, like fuels or plastics.

22 citations

US 8636880· 2009· Atomic Energy of Canada Ltd AECL

How to Make Hydrogen Gas and Cupric Chloride Using an Electrolysis Cell

This patent describes an electrochemical cell that uses cuprous chloride in hydrochloric acid to produce hydrogen gas and cupric chloride, separated by a special membrane.

3 citations

2010s

US 8049150· 2010· Skyline Solar

How to Make Solar Troughs Catch More Sunlight at Their Ends

This patent describes adding special reflective extensions and caps to the ends of a single-axis tracking solar trough to capture more sunlight that would otherwise be lost, making the collector more efficient.

23 citations

US 9181624· 2010· Chlorine Engineers Corp

Making Caustic Soda with Less Salt Using a Special Electrolysis Cell

This patent describes a method to make purer caustic soda and chlorine gas using a two-chamber electrolysis cell with a gas diffusion electrode by carefully controlling pressure differences.

7 citations

US 9055681· 2012· International Business Machines

Attaching Flexible Circuits with Light Sensors to a Chip

This patent describes a method and device for attaching a bendable circuit, which includes light-sensing or light-emitting components, onto a main chip, allowing light to pass through a hole in the chip to reach the flexible part.

US 8496208· 2013· Alliant Techsystems Inc

How Spacecraft Use Layered Nets to Stop Orbital Debris

A system using multiple layers of specialized fiber nets with varying densities to catch and break up space junk before it hits a satellite.

3 citations

US 9256834· 2013· Microsoft Technology Licensing

How Quantum Computers Use Special Devices to Control Qubits

This patent describes a way for quantum computers to control special quantum bits, called topological qubits, using a "partial interferometric device" to perform specific operations.

12 citations

US 10525078· 2014· Tomita Pharmaceutical Co Ltd

How to Make Stable Solid Dialysis Powder with Less Odor

A specialized solid powder mixture used to create dialysis fluid that stays stable, smells less like vinegar, and keeps acetate levels within a precise, safe range.

US 10593988· 2015· GM Global Technology Operations

Improving Lithium Battery Life with a Built-in Lithium Source

This patent describes a method for building rechargeable lithium-based batteries with a special extra lithium source electrode inside that helps the main battery parts work better and last longer by giving them an initial charge of lithium ions.

11 citations

US 10522884· 2016· Worcester Polytechnic Institute

Recycling Lithium-Ion Batteries to Make New Cathode Materials

This patent describes a method for recycling used lithium-ion batteries by dissolving their cathode materials, adjusting the metal ratios in a liquid, and then pulling out a custom mix of materials for new batteries without needing extreme heat.

9 citations

US 10468695· 2017· SolidPower SA

How Fuel Cells Get Even Gas Flow with Special Layers

This patent describes a fuel cell component that uses a special two-layer design with linear channels and transverse openings to evenly spread fuel gas for better performance.

1 citation

US 10566652· 2017· GM Global Technology Operations

How a Hybrid Layer Stops Metal Growths in Lithium Batteries

This patent describes a special multi-layered electrolyte system for lithium metal batteries that uses a stiff, hybrid material to block dangerous metal growths, aiming for safer, higher-energy batteries.

13 citations

US 20180127759· 2017· Massachusetts Institute of Technology

Highly Efficient Bacterial Gene Editing Using Guide RNA and Reverse Transcriptase

This patent describes a system for precisely editing the DNA of bacterial cells with very high success rates, using a combination of guide RNA, reverse transcriptase, and specific DNA sequences.

30 citations

US 12350368· 2018· Massachusetts Institute of Technology

Delivering Large Gene Editing Tools into Cells with Hybrid Virus-Lipid Packages

This patent describes a sophisticated delivery system that combines parts of a virus with a fat bubble (liposome) to efficiently transport large molecules, like CRISPR gene-editing components, into specific cells.

US 10514610· 2018· Taiwan Semiconductor Manufacturing Co TSMC

Making Tiny Chip Patterns Using Gas and Light

This patent describes an advanced machine that uses a special gas and patterned light, like a tiny stencil, to draw incredibly small features directly onto a silicon wafer for making computer chips.

US 11239459· 2018· GM Global Technology Operations

Making Solid-State Battery Electrodes That Don't Swell and Crack

This patent describes a special design for solid-state battery electrodes that uses tiny internal holes and spaces between particles to prevent them from expanding and cracking during charging and discharging.

6 citations

US 11311959· 2018· Meld Manufacturing

Building Metal Parts Without Melting: Solid-State 3D Printing System

This patent describes a system for building or repairing metal parts by frictionally heating and stirring materials together without melting them, precisely controlling the material's internal structure as it's made.

18 citations

US 20190160160· 2019· Individual

Making Drug Proteins Last Longer and Target Diseases Better

This patent describes ways to make protein and peptide drugs stay in the body longer and target specific diseases like autoimmune conditions or cancer more precisely by linking them together or combining them with other molecules.

US 11134620· 2019· Individual

Using Special Mud to Help Plants Grow Better

This patent describes a method using a super-saturated bentonite clay mud mixture to improve plant growth, especially in dry conditions, by retaining more moisture than regular soil.

1 citation

US 11267584· 2019· Airbus Operations SL

How to Build an Aircraft Tail Using One-Shot Composite Curing

A manufacturing process for creating an aircraft's rear fuselage and vertical tail as a single, integrated composite structure to reduce weight and assembly time.

US 11794927· 2019· Boeing Co

How Boeing 3D Prints Strong Lightweight Spacecraft Panels

A method for printing a single-piece, high-strength spacecraft panel using 3D printing to create complex internal trusses that eliminate the need for bolts or welds.

US 11145922· 2019· GM Global Technology Operations

Boosting Solid-State Batteries with a Capacitor Interlayer

This patent describes a solid-state battery design that includes a special capacitor-like layer between the main battery parts to improve performance and stability.

14 citations

US 11137298· 2019· University of California San Diego UCSD

How Fabric Sensors Measure Pressure on Your Body

This patent describes a flexible, all-fabric sensor that uses special ionic and conducting materials woven into a cloth to detect tiny pressure changes on the body, like blood pulses or movements.

US 12031028· 2019· LG Chem Ltd

How LG Chem Makes Plastic Films That Block UV Light

A specialized plastic film made of alternating chemical segments that blocks harmful ultraviolet light while remaining perfectly clear.

US 11417435· 2019· GE Hitachi Nuclear Energy Americas

How a Nuclear Reactor's Rotating Drum Controls Power

This patent describes a rotating drum for nuclear reactors, especially mobile ones, that uses tubes filled with different materials to absorb or scatter neutrons, precisely controlling the reactor's power output.

8 citations

2020s

US 12178901· 2020· Conopco Inc

How Light-Activated Polymers Deliver Skin Care Ingredients

A chemical structure that holds onto skin-care ingredients like fragrances or cooling agents and releases them only when triggered by specific light conditions.

US 20210123152· 2020· National Chung Shan Institute of Science and Technology NCSIST

How to Make Big Electrodes for Splitting Water

This patent describes a simple, energy-saving way to create large, efficient catalyst electrodes using a mix of iron, cobalt, and nickel compounds through an electrical plating process.

21 citations

US 10962473· 2020· Notco Delaware

AI Model Predicts Protein Shapes from Infrared Light Data

This patent describes a computer method that uses an artificial intelligence model to predict the detailed 3D shapes of proteins within a food ingredient by analyzing how the ingredient absorbs infrared light.

14 citations

US 20210174903· 2020· Protein Evolution

How to Predict Protein Shapes Better Using Lab Tests and Computers

This patent describes a method to improve predicting a protein's 3D shape by combining computer simulations with actual distance measurements from specific parts of the protein in a lab.

21 citations

US 12086666· 2020· Covestro Deutschland AG

How to Make Reusable Plastic SIM Card Holders

A design for a plastic card that allows users to pop out and snap back in different sizes of SIM cards without them falling out.

US 11171521· 2020· Voice Life

How a Device Receives Wireless Power Using Terahertz Waves and Blockchain

This patent describes a receiver device that wirelessly collects terahertz electromagnetic energy using special materials and an antenna, then converts it to electricity, but only after a transmitter authenticates it using a blockchain.

US 12134567· 2021· Powdertech Co Ltd

How to Make Better Ferrite Powder for Industrial Use

A specific recipe for creating highly spherical magnetic ferrite particles that mix easily into plastics without ruining the curing process.

US 11728052· 2021· Terra Power

TerraPower's Molten Salt Reactor with Internal Heat Exchangers

This patent describes a unique molten salt nuclear reactor design by TerraPower, featuring an open-topped vessel and integrated heat exchangers for efficient internal cooling and fuel circulation.

1 citation

US 12266789· 2021· Seoul National University R&DB Foundation

How to Make Lithium-Sulfur Batteries Last Longer Using Polymer Coatings

A new way to coat sulfur battery cores with a special polymer to prevent them from degrading, helping them hold a charge for more cycles.

US 11905044· 2021· LGarde Inc

How Solar Sails Use Moving Vanes to Steer in Space

A solar sail design that uses multiple independently moving reflective vanes made of shape-memory materials to steer spacecraft using only the pressure of sunlight.

7 citations

US 11942620· 2021· GM Global Technology Operations

How to Build Solid-State Batteries with Tiny Holes for Better Electrolyte

This patent describes a method for manufacturing solid-state batteries by punching small holes through battery electrodes and then filling these holes with a liquid that hardens into a solid electrolyte, aiming for more efficient power delivery.

2 citations

US 20220304938· 2022· Nanosphere Health Sciences

Tiny Lipid Balls for Precise, Better-Absorbed Cannabinoid Medicine

This patent describes a drug delivery system using tiny lipid nanoparticles to encapsulate cannabinoids, making them easier for the body to absorb and allowing for precise, smaller doses.

US 12043450· 2022· Inteplast Group Corp

How to Make Waste-Free Plastic Grocery Bags on a Roll

A design for plastic grocery bags on a roll that eliminates leftover scrap material during manufacturing while allowing users to easily tear off and open handles.

US 20250027216· 2022· Individual

Dome-Shaped Plates for Efficient Hydrogen Production in Electrolyzers

This patent describes an electrolyzer that uses uniquely dome-shaped plates to improve how water is split into hydrogen and oxygen, enhancing efficiency and product separation.

1 citation

US 20240109245· 2023· Meld Manufacturing

How to Precisely Control Solid-State 3D Printing for Stronger Materials

This patent describes a system for precisely controlling solid-state additive manufacturing, allowing real-time adjustments to create specific material structures without melting, using continuous material feeds.

9 citations

US 12358049· 2024· Desktop Metal

How to 3D Print Metal Parts with Easy-to-Remove Supports

This patent describes a method for 3D printing complex metal objects with support structures that can be easily removed after the final part is made solid, by using a special non-stick layer in between.

1 citation

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