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PatentBrief

Innovation Timeline

Advanced Materials

Gore-Tex, carbon fiber, nanotubes, and the materials science patents that created entirely new industries.

Landmark patents

67

Total citations

12,865

Span

18442022

Milestones

14

1840s

1850s

1860s

1870s

1880s

1890s

1900s

1910s

1920s

1930s

US 1967861· 1931· EI Du Pont de Nemours and CoPublic domain

How DuPont Invented Neoprene Synthetic Rubber

A 1934 patent describing the chemical process to turn chlorobutadiene into a durable, oil-resistant synthetic rubber known as Neoprene.

7 citations

US 2133235· 1933· Owens Illinois Glass CoPublic domain

How Glass Fibers Are Spun for Insulation

A 1933 invention by Games Slayter that describes the process of melting glass and blasting it into fine, flexible fibers to create insulation.

22 citations

Milestone
US 2130523· 1935· EI Du Pont de Nemours and CoPublic domain

How Wallace Carothers Invented Nylon

The foundational 1935 patent for synthetic linear polyamides, the chemical process that created the material we now call nylon.

299 citations

Milestone
US 2297691· 1939· IndividualPublic domain

Chester Carlson's Original Xerography Patent

Chester Carlson's 1942 patent for xerography, the dry copying process that became the foundation for Xerox machines.

737 citations

US 2230654· 1939· KINETIC CHEMICALS IncPublic domain

The Discovery of Teflon

This 1941 patent describes the creation of polytetrafluoroethylene, a slippery, heat-resistant plastic discovered by accident that became known as Teflon.

74 citations

1940s

1950s

US 2682235· 1951· IndividualPublic domain

Buckminster Fuller's Geodesic Dome Building Design

A structural design for a spherical building made of interlocking triangular frames that distribute weight efficiently to create large, stable, and lightweight spaces.

120 citations

Milestone
US 2717437· 1952· Velcro SAPublic domain

How George de Mestral Invented Velcro

A 1952 patent describing the creation of a hook-and-loop fastener by weaving synthetic loops into fabric and cutting them to create tiny, grippy hooks.

299 citations

US 2768109· 1954· Eastman Kodak CoPublic domain

How Super Glue Bonds Acidic Surfaces Like Wood

A 1954 method for using alcohol to help super glue stick to acidic surfaces like wood, which normally prevent the glue from hardening properly.

23 citations

US 2911759· 1954· Pilkington Brothers LtdPublic domain

How the Float Glass Process Makes Perfectly Flat Window Panes

This 1954 patent describes the float glass process, a method for creating high-quality, perfectly flat glass by floating molten glass on a bath of liquid metal.

53 citations

US 2929804· 1955· EI Du Pont de Nemours and CoPublic domain

How Spandex Elastic Fibers Are Chemically Engineered

DuPont's 1960 patent for a stretchy, durable synthetic fiber made from segmented polymers, which became the foundation for modern Spandex.

71 citations

US 3142599· 1959· Sealed Air CorpPublic domain

How Bubble Wrap Is Manufactured

A 1959 manufacturing process that creates cushioning material by trapping air between two layers of plastic film.

185 citations

1960s

US 3220960· 1960· IndividualPublic domain

How Soft Contact Lenses Were Invented Using Hydrogels

This patent describes the chemical recipe for soft, water-absorbing plastic materials that form the basis of modern soft contact lenses.

228 citations

US 3322485· 1962· RCA CorpPublic domain

How Liquid Crystal Displays (LCDs) Were Invented

This 1962 patent describes the first practical way to use organic liquid crystals to create a display that scatters light when an electric current is applied.

90 citations

US 3489148· 1966· Procter and Gamble CoPublic domain

How Disposable Diapers Keep Skin Dry Using Porous Plastic Sheets

A 1970 patent by Procter and Gamble describing a specialized plastic top layer for diapers that allows liquid to pass through while keeping the baby's skin feeling dry.

133 citations

US 3671542· 1969· EI Du Pont de Nemours and CoPublic domain

How Stephanie Kwolek Invented the Liquid Crystal Solution for Kevlar

A 1969 chemical discovery describing a specialized liquid mixture that allows for the creation of incredibly strong, high-performance synthetic fibers.

132 citations

1970s

Milestone
US 3691140· 1970· IndividualPublic domain

Sticky, Tiny Plastic Balls Made from Acrylates

This 1972 patent describes how to make tiny, sticky, and durable plastic balls (microspheres) using a specific mix of acrylate chemicals and a special water-based process.

382 citations

US 3711262· 1970· Corning Glass WorksPublic domain

How Corning Invented Modern Fiber Optic Cables

A 1970 method for creating glass fibers that carry light over long distances by layering glass inside a tube and drawing it into a thin, solid strand.

86 citations

Milestone
US 3946398· 1970· SILONICS IncPublic domain

How Piezoelectric Inkjet Printing Works

A 1970 patent describing how to print images by using electrical pulses to bend a tiny crystal plate, squeezing individual ink drops out of a nozzle on demand.

448 citations

US 3733309· 1970· EI Du Pont de Nemours and CoPublic domain

How Plastic Soda Bottles Are Made Stronger Using Stretched Molecules

A 1970s invention that describes how to make lightweight, clear plastic bottles strong enough to hold carbonated drinks without exploding.

170 citations

US 3778335· 1971· Corning Glass WorksPublic domain

How Chemically Strengthened Glass Works

A 1971 Corning patent describing a specific chemical recipe for glass that can be made incredibly tough by swapping small atoms in its surface for larger ones.

52 citations

US 3819587· 1971· EI Du Pont de Nemours and CoPublic domain

The Molecular Structure of Kevlar High-Strength Fiber

Stephanie Kwolek's 1971 patent for DuPont describing the molecular alignment and manufacturing of extremely strong, lightweight synthetic aramid fibers, which became famous as Kevlar.

141 citations

Milestone
US 3953566· 1973· WL Gore and Associates IncPublic domain

Making Strong, Porous PTFE: The Gore-Tex Process

This patent describes a specific process for rapidly stretching a highly crystalline form of PTFE plastic to create a strong, porous material with a unique internal structure, forming the basis for products like Gore-Tex.

1,364 citations

US 4009052· 1976· Exxon Research and Engineering CoPublic domain

Early Lithium-Ion Battery Design Using Chalcogenides

This 1977 patent describes an early rechargeable battery design using lithium as one electrode and titanium disulfide as the other, a key step towards modern lithium-ion technology.

93 citations

Milestone
US 4166152· 1977· Minnesota Mining and Manufacturing CoPublic domain

The Sticky Microscopic Beads Behind Post-it Notes

3M's 1977 patent on tiny, naturally sticky plastic beads that can stick to a surface, peel off easily without leaving residue, and be reused over and over again.

278 citations

Milestone
US 4235871· 1978· Individual

How to Encapsulate Active Materials in Lipid Bubbles Efficiently

This patent describes a method for trapping biologically active substances inside tiny, multi-layered fat bubbles called liposomes, using a specific water-in-oil emulsion and gel-forming process to improve how much material gets captured.

1,862 citations

US 4267420· 1978· General Mills IncPublic domain

How Microwave Crisping Sleeves Work

General Mills' 1978 patent on using a thin, metal-coated plastic wrap that converts microwave energy into intense surface heat to crisp and brown food like Hot Pockets.

234 citations

1980s

US 4302518· 1980· IndividualPublic domain

How Lithium-Cobalt Battery Cathodes Were Invented

This 1981 patent details the chemistry behind the lithium-cobalt oxide cathodes that power almost every modern smartphone, laptop, and electric vehicle.

90 citations

Milestone
US 4356429· 1980· Eastman Kodak CoPublic domain

How Organic Diodes Make Light Using Special Molecules

Eastman Kodak's 1982 patent on creating light-emitting diodes (OLEDs) using organic materials, specifically a layer of porphyrinic compounds to help inject electrical charges.

1,031 citations

US 4357215· 1981· IndividualPublic domain

How Lithium-Ion Battery Cathodes Are Made

A foundational 1982 method for creating the materials used in rechargeable lithium-ion batteries by removing ions at low temperatures.

41 citations

Milestone
US 4575330· 1984· UVP IncPublic domain

How 3D Printers Build Objects Layer by Layer from Liquid

This patent describes the foundational method for 3D printing, where a machine builds a three-dimensional object layer by layer by hardening a liquid material with light or other energy.

1,094 citations

Milestone
US 4727064· 1985· US Department of Health and Human Services

How Special Sugars Make Medicines Dissolve Better

This patent describes how to make poorly water-soluble drugs dissolve and absorb better by mixing them with specially modified, non-crystalline sugar molecules called cyclodextrin derivatives.

341 citations

US 4810490· 1987· Carter Wallace Inc

How to Make Clear, Waterproof Sunscreen That Doesn't Feel Greasy

A 1989 patent for a transparent, water-resistant sunscreen formula that uses wood rosin to create a non-sticky, long-lasting protective film on the skin.

11 citations

Milestone
US 5121329· 1989· Stratasys IncPublic domain

How Machines Build 3D Objects Layer by Layer from Melting Plastic

This patent describes a method and machine for creating three-dimensional objects by precisely depositing melted material, layer by layer, from a movable nozzle onto a base.

793 citations

1990s

US 5272135· 1991· Chiron Ophthalmics Inc

Preventing Protein Damage with Extra Methionine

This 1993 patent describes how adding extra methionine to protein-based medicines can prevent them from degrading, especially in liquid or semi-solid forms.

63 citations

US 5401560· 1993· Norton CoPublic domain

How to Make Durable Non-Slip Surfaces Using Electron Beam Curing

A method for creating flexible, non-slip materials by bonding mineral grit to plastic sheets using a special radiation-cured glue that stays strong even when stretched.

25 citations

Milestone
US 6267958· 1996· Genentech Inc

Making High-Concentration Antibody Medicines Stable for Injection

Genentech's 2001 patent on a method to create stable, concentrated antibody medicines that can be easily reconstituted for injection, preventing degradation during freezing and storage.

878 citations

Milestone
US 5961804· 1997· Massachusetts Institute of TechnologyPublic domain

Tiny Capsules for Electronic Paper Displays

MIT's 1999 patent on a special ink made of tiny capsules that can change color when an electric field is applied, forming the basis for early e-readers.

508 citations

US 6033785· 1997· Central Glass Co LtdPublic domain

How Car Windows Use Special Coatings to Balance Privacy and Visibility

A patent for automotive glass that uses a specific combination of tinted glass and multi-layered coatings to keep the inside private while ensuring the driver can see out clearly.

7 citations

2000s

US 6793929· 2000· Beiersdorf AG

How to Make Stable, High-Water Content Skin Creams

A recipe for creating stable skin lotions that are mostly water but feel like rich, oily creams by using specific silicone emulsifiers and carefully balanced oils.

25 citations

US RE39497· 2001· Nektar Therapeutics

How to Store Fragile Biological Materials Without Refrigeration

A method for preserving unstable biological materials like proteins by trapping them in a solid, glass-like sugar or polymer matrix that prevents decay at room temperature.

11 citations

US 8156057· 2008· Knowmtech

How Nanoparticles Form Adaptive Neural Network Connections

This patent describes how to build and strengthen a physical neural network using tiny nanoparticles suspended in a liquid, where electric fields make the connections learn and adapt.

12 citations

2010s

US 8496208· 2013· Alliant Techsystems Inc

How Spacecraft Use Layered Nets to Stop Orbital Debris

A system using multiple layers of specialized fiber nets with varying densities to catch and break up space junk before it hits a satellite.

3 citations

US 10525078· 2014· Tomita Pharmaceutical Co Ltd

How to Make Stable Solid Dialysis Powder with Less Odor

A specialized solid powder mixture used to create dialysis fluid that stays stable, smells less like vinegar, and keeps acetate levels within a precise, safe range.

US 20180127759· 2017· Massachusetts Institute of Technology

Highly Efficient Bacterial Gene Editing Using Guide RNA and Reverse Transcriptase

This patent describes a system for precisely editing the DNA of bacterial cells with very high success rates, using a combination of guide RNA, reverse transcriptase, and specific DNA sequences.

30 citations

US 11267584· 2019· Airbus Operations SL

How to Build an Aircraft Tail Using One-Shot Composite Curing

A manufacturing process for creating an aircraft's rear fuselage and vertical tail as a single, integrated composite structure to reduce weight and assembly time.

US 11794927· 2019· Boeing Co

How Boeing 3D Prints Strong Lightweight Spacecraft Panels

A method for printing a single-piece, high-strength spacecraft panel using 3D printing to create complex internal trusses that eliminate the need for bolts or welds.

US 12031028· 2019· LG Chem Ltd

How LG Chem Makes Plastic Films That Block UV Light

A specialized plastic film made of alternating chemical segments that blocks harmful ultraviolet light while remaining perfectly clear.

2020s

US 12178901· 2020· Conopco Inc

How Light-Activated Polymers Deliver Skin Care Ingredients

A chemical structure that holds onto skin-care ingredients like fragrances or cooling agents and releases them only when triggered by specific light conditions.

US 12086666· 2020· Covestro Deutschland AG

How to Make Reusable Plastic SIM Card Holders

A design for a plastic card that allows users to pop out and snap back in different sizes of SIM cards without them falling out.

US 12134567· 2021· Powdertech Co Ltd

How to Make Better Ferrite Powder for Industrial Use

A specific recipe for creating highly spherical magnetic ferrite particles that mix easily into plastics without ruining the curing process.

US 12266789· 2021· Seoul National University R&DB Foundation

How to Make Lithium-Sulfur Batteries Last Longer Using Polymer Coatings

A new way to coat sulfur battery cores with a special polymer to prevent them from degrading, helping them hold a charge for more cycles.

US 11905044· 2021· LGarde Inc

How Solar Sails Use Moving Vanes to Steer in Space

A solar sail design that uses multiple independently moving reflective vanes made of shape-memory materials to steer spacecraft using only the pressure of sunlight.

7 citations

US 12043450· 2022· Inteplast Group Corp

How to Make Waste-Free Plastic Grocery Bags on a Roll

A design for plastic grocery bags on a roll that eliminates leftover scrap material during manufacturing while allowing users to easily tear off and open handles.

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